Does carbon dioxide or methane of them caused ozone hole and how?

methane causes ozone hole because it is more poisonous than carbon dioxide

I hope it help u

the work done by the gas can be determined by working out the force applied by the gas and calculating the distance. however, the force applied by the gas is the pressure times the area, so: w = f s = p a s. and the area multiplied by the distance is a volume, specifically the change in volume of the gas